ACS ES&T Air | 利用互补质谱技术研究中国西部两个特大城市有机气溶胶的组成和来源

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Composition and Sources of Organic Aerosol in Two Megacities in Western China Using Complementary Mass Spectrometric and Statistical Techniques （ 由于标题字数限制， 中文标题为自翻，以原标题为准） Abstract Over 300 daily PM2.5 filter samples were collected in two western Chinese megacities, Xi’an and Chongqing, from October 2019 to May 2020. Their aqueous extracts were nebulized simultaneously to an aerosol mass spectrometer (AMS) and a recently developed extractive electrospray ionization (EESI) mass spectrometer, for bulk and near-molecular organic aerosol (OA) composition, respectively. Carbonate was quantified using EESI and a total organic carbon analyzer to separate inorganic carbon from dust. Via isotopically-labelled internal standards and positive matrix factorization, seven water-soluble sources were quantified separately using the AMS- and EESI-based analyses, with consistent types, concentrations, and correlations. These include dust, solid fuel c ………………………………